In reply to ProDarwin :
Two things- why do you assume that there's not a markup for the aftermarket? Their investment in making "replacement" parts is actually a lot higher per part than OEM's, as we just make more of hte original part, and the remaining cost is just storage of the parts for 10 years. We don't make any money on replacement parts- the market is just too small relative to making new cars.
So in terms of efficiency- for the upcoming rules, (as that's what I track, not old ones) compared to the standard, the catalysts are just over 99% efficient on average for the entire test. For the most part, vehicles put out ~8 g/mi of NMOG + NOx, and we will be allowed 0.030 g/mi over the same test. In reality, the cars are actually putting out 0.02-0.025 g/mi at 150k, just to be safe.
The allowance for lighting a light is 1.5x the standard, or 0.045g/mi. So while the cars are designed to meet a low target, the rule makers allow more until a fault is noted. This math is essentially the same for whatever standard for the last 20 years- so for a ULEVII that would be 0.090g/mi standard, allowance up to 0.135 g/mi until a fault is noted.
In terms of how they fail, it's pretty gradual for normal wear. The only why catalyst suddenly fail is misfire (which is sort of protected) and physical damage. The rest is just a slow failure, mostly from heat and phosphorus poisonoing.
Still, the aftermarket mark up is there, which gives you an idea how cheap the parts are. If one is lucky, then the part you buy is the same manufacturer of the part for the OEM- which saves a little money. Many of those parts fail OEM QC standards, but are ok for the aftermarket.
The standard for the aftermarket is that they are supposed to demonstrate the original emission standard when they are brand new, and that's it. I'm not sure how rigorous the process is to prove it, but it's still not the same as OE. But that is supposed to protect catalysts for specific packages as opposed to general, universal, replacements.
There are some cars and emissions standards tha have a "universal fit" replacement- but as time goes on, and standards have gotten lower, and poor replacement parts are found- that will be less and less over time.